Inorganic Polymers Containing Re(CO)3L

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General Book Search for "9781616689285"

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Inorganic Polymers Containing -Re(CO)3L+ Pendants

Author : Ezequiel Wolcan,Mario R Feliz
Paperback
Published : Tuesday 8 February 2011
ISBN : 9781616689285
Price : €72.53

Description

This book describes the synthesis, photophysical and photochemical properties of inorganic polymers containing-Re(CO)3L+ pendants. Marked differences were found between the photochemical and photophysical properties of the polymers and those of the related monomeric complexes, pyRe(CO)3L+ (py = pyridine). The main cause of these differences is the photogeneration of the metal-to-ligand charge transfer (MLCT) excited sates in concentrations that are much larger when -Re(CO)3 L+ chromophores are bound to (vpy)n~600.